Since the discovery of Sodium acetate was probably an accident it would be difficult to pin point the exact date, location, person and time as per its invention. The best guess is that its discovery was made in ancient times by someone who mixed ashes from a fire with vinegar by accident.
The acetic acid or vinegar was what led to the discovery of the first know to be Hot ice. When vinegar mixed with the ashes it helped prepare leather. This solution was know as sodium acetate.
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